en Research Paper Research Paper <div>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; In this study we have synthesis the Zr substituted BaTi_0.80Fe_0.20O₃ceramics at different content of Zr from x=0.00 to 0.10 by using the solid-state route. The room temperature X-ray diffraction results confirmed the coexistence of the two tetragonal and hexagonal phases for x &le; 0.050 of Zr content. While above 0.050 the hexagonal phase disappears in benefit of tetragonal phase. The Raman results confirmed the formation of these phases obtained with XRD. The scanning electron micrographs consist of both spherical and straight grain forms for x=0.000 to 0.075, and only spherical grain form for x=0.100 attributed to the tetragonal phase. Also, the grain size increases accompanied with a decrease in density of ceramics with increasing Zr content up to 0.050 then decreases accompanied with an increase in density. Detailed studies of dielectric permittivity measurement have provided a presence of two anomalies T_e and T_R-O at different temperatures, with a relaxation phenomenon and diffuse behavior which is very important for ceramic at x=0.075 of Zr content. The dielectric permittivity values of the two anomalies of Zr substituted BaTi_0.80Fe_0.20O₃ceramics increase with increase of Zr content and the dielectric loss is minimal at x=0.100 of Zr content. The conductivity increases with the increasing of Zr substitution from 0.025 to 0.075 levels while for x = 0.100 the dielectric conductivity decreases.&nbsp; And the Cole-Cole analysis indicates a negative thermal resistivity coefficient (NTCR) behavior of these materials and an ideal Debye-type behavior.</div> Solid-state,X-ray diffraction,Raman,dielectric permittivity,anomalies,relaxation,diffuse,conductivity,Cole-Cole. 1 12 http://ijmse.iust.ac.ir/browse.php?a_code=A-10-3303-2&slc_lang=en&sid=1 Najwa Gouitaa najwa.gouitaa@gmail.com 1800319475328460014710 1800319475328460014710 Yes Signals, Systems and Components Laboratory (LSSC), Electrical Engineering Department, University Sidi Mohamed Ben Abdellah USMBA, FST. Fez, Imouzzer Road B.P. 2202, Morocco Lamcharfi Taj-dine 1800319475328460014711 1800319475328460014711 No Signals, Systems and Components Laboratory (LSSC), Electrical Engineering Department, University Sidi Mohamed Ben Abdellah USMBA, FST. Fez, Imouzzer Road B.P. 2202, Morocco Abdi Farid 1800319475328460014712 1800319475328460014712 No Signals, Systems and Components Laboratory (LSSC), Electrical Engineering Department, University Sidi Mohamed Ben Abdellah USMBA, FST. Fez, Imouzzer Road B.P. 2202, Morocco Ahjyaje Fatima Zahra 1800319475328460014713 1800319475328460014713 No Signals, Systems and Components Laboratory (LSSC), Electrical Engineering Department, University Sidi Mohamed Ben Abdellah USMBA, FST. Fez, Imouzzer Road B.P. 2202, Morocco