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Showing 4 results for Activation Energy.
SOLID STATE REDUCTION OF CHROMITE IN HIGH CARBON FERROCHROMIUM-CHROMITE COMPOSITE PELLETS
A. Ataie1,, S. Heshmati-Manesh1,, S. Sheibani1,, G. R. Khayati,y. Firozbakht,
Volume 5, Issue 1 (3-2008)
Abstract
Abstract: In this paper solid state reduction of high carbon ferrochromium-chromite composite pellets in the temperature range of 900-1350°C was investigated. A two stage reduction mechanism is proposed. The first stage is likely to be controlled by the chemical reaction with activation energy of 127.2kJ/mol. In the second stage, solid state diffusion of carbon through the reaction product layer is suggested to be rate controlling. The activation energy of this stage was calculated to be 93.1kJ/mol. The reduction process was found to be favored by high temperatures as well as high vacuum. The results also show that pre-milling of initial mixture has a negative effect on the reduction degree.
FORMATION AND GROWTH OF TITANIUM ALUMINIDE LAYER AT THE SURFACE OF TITANIUM SHEETS IMMERSED IN MOLTEN ALUMINUM
R. Khoshhal, M. Soltanieh, M. Mirjalili,
Volume 7, Issue 1 (3-2010)
Abstract

Abstract:

titanium sheets in pure molten aluminum at 750

and X-Ray Diffraction Analysis results, TiAl

intermetallic layer thickness increases slowly at primary stages. After that an enhanced growth rate occurs due to layer

cracking and disruption. Presumably, reaction starts with solving titanium into the molten aluminum causing in

titanium super saturation and TiAl

intermetallic layer which consequently leads to TiAl

energy of intermetallic layer formation and growth was developed by measuring titanium thickness decreases.

In this work, kinetics of intermetallic compounds formation in Al-Ti system was studied by immersingoC, 850 oC and 950 oC. According to Scanning Electron Microscopy3 is the only phase can form at the interface. Observations revealed that3 formation. At this stage, growth may be controlled by aluminum diffusion through3 formation at the interface of Ti-TiAl3. Furthermore, activation
EFFECTOFTHE TYPE OFCARBON MATERIALON THE REDUCTION KINETICS OFBARIUM SULFATE
M. Sh. Bafghi, A. Yarahmadi, A. Ahmadi, H. Mehrjoo,
Volume 8, Issue 3 (9-2011)
Abstract

Abstract:

the reduction agent. Pellets of barite ore containing about 95% BaSO

temperature, time, ore grain size and the type and grain size of the carbon materials. Graphite, coke and charcoal have

been used as the reducing agent and the reduction experiments have been performed in the temperature range of 925-

1150 °C. Apart from conducting the experiments using pellets made of ore powder, kinetic analysis of the experimental

data by use of the reduced (dimensionless) time method has been another unique feature of the present study.

Experimental results show that grain size of either carbon material or barite ore has not appreciable effect on the

reaction rate. Kinetic analysis of the experimental data revealed the rate is strongly controlled by the chemical reaction

of carbon gasification (Boudouard reaction). The reaction rate is very considerably related to the type of carbon

material so that the activation energy varies from 15.6 kcal.mol

kcal.mol

gasification.

The present study deals with the reduction of barium sulfate (Barite) to barium sulfide by use of carbon as4 has been reduced under different conditions of-1 for charcoal to 26.3 kcal.mol-1 for graphite and 20.8-1 for coke. This behavior provides further support for the postulated reaction mechanism, i.e., carbon
THERMAL ANALYSIS AND KINETICS OF THE PRECIPITATION IN WROUGHT Al-Mg, Al-Mg-ScAND Al-Mg-Sc-Me (Me=Zr, Ti) ALLOYS
M. S. Kaiser,
Volume 10, Issue 3 (9-2013)
Abstract
Precipitation behaviour of wrought Al-6Mg alloys with ternary scandium and quaternary zirconium and titanium has been studied. Hardness measurements and resistivity studies are employed to assess the precipitation behaviour of scandium doped Al-6Mg alloy without or with quaternary additions of zirconium and titanium. Further, the kinetics of precipitations are studied by differential scanning calorimetric technique. Scandium has been observed to form fine coherent Al3Sc precipitates during ageing and these are responsible for strengthening of the alloys. The precipitation kinetics of Al3Sc depends on the diffusion of scandium in aluminium. Presence of fine coherent precipitates of Al3Sc impedes the migration of dislocations and increase the recovery temperature. The kinetics of recrystallisation is also delayed.
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