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Showing 2 results for Roy

A. R. Hanifi,, A. Genson, M. J. Pomeroy, S. Hampshire,
Volume 7, Issue 1 (winter 2010 2010)

Oxynitride glasses are found as grain boundary phases in silicon nitride ceramics. They are effectively alumino-silicate glasses in which nitrogen substitutes for oxygen in the glass network, and this causes increases in glass transition and softening temperatures, viscosities (by two to three orders of magnitude), elastic moduli and microhardness. Calcium silicate-based glasses containing fluorine are known to have useful characteristics as potential bioactive materials. Therefore, the combination of both nitrogen and fluorine additions to these glasses may give useful glasses or glass-ceramics with enhanced mechanical stability for use in biomedical applications. This paper reports glass formation and evaluation of glass thermal properties in the Ca-Si-Al-O-N-F system. Within the previously defined Ca-Si-Al-O-N glass forming region at 20 eq.% N, homogeneous, dense glasses are formed. However, addition of fluorine affects glass formation and the reactivity of glass melts. This can lead to fluorine loss as SiF4, and also nitrogen loss, leading to bubble formation and porous glasses. The compositional limits for both dense
and porous glass formation at 20 eq.% N and 5 eq.% F have been mapped. At high fluorine contents under conditions when Ca-F bonding is favoured, CaF2 crystals precipitate in the glass. The role of the different cations on glass formation in these oxyfluoro-nitride glasses is discussed.

T. Mandal, D. Roy,
Volume 17, Issue 1 (March 2020)

Magnetic iron oxide nanomaterials (MIONs) have been extensively investigated for the various important applications. Coprecipitation, hydrothermal, high temperature decomposition of organic precursors, microemulsions, polyol methods, electrochemical methods, aerosol method, sonolysis and green synthesis processes for the fabrication of MIONs have been reviewed. Different characterization methods like XRD, SEM, EDX and TEM for the as prepared MION materials have been studied. Important applications of MIONs in the field of biomedical, nanorobotics and energy devices have also been addressed in this review. Target oriented drug delivery and hyperthermia applications of MIONs have also focused

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